Nitroxyl (HNO) is emerging as a significant reactive nitrogen species with unique chemical and biological properties distinct from its congener nitric oxide. Its chemistry is characterised by a ...

The development of 1,5-dimethyl-9-azanoradamantane N-oxyl (DMN-AZADO; 1,5-dimethyl-Nor-AZADO, 2) as an efficient catalyst for the selective oxidation of primary alcohols in the presence of secondary ...

In this report, we describe proton-coupled electron transfer (PCET) reactivity at the surface of the Keggin-type polyoxotungstate cluster [nBu4N]3[PWVI12O40] (PW12) in acetonitrile. Bond dissociation ...

Azanone (HNO, also known as nitroxyl) is the protonated form of the product of one-electron reduction of nitric oxide (• NO), and an elusive electrophilic reactive nitrogen species of increasing ...